122606-10-4

Upstream product

• 122606-06-8 1-(phenylthio)methyl-3,5-dimethyl-1H-pyrazole 
• 108-98-5 thiophenol 
• 91979-38-3 1-chloromethyl-3,5-dimethyl-1H-pyrazole hydrochloride 
• 7205-91-6 phenylthiomethyl chloride 
• 67-51-6 3,5-dimethyl-1H-pyrazole 

Downstream Products

• 122606-14-8 3,5-dimethyl-1-styryl-1H-pyrazole 
• 122606-19-3 2-(3,5-dimethyl-1H-pyrazol-1-yl)-1-(4-methylphenyl)-2-phenylsulfinylethan-1-ol 

Relevant academic research and scientific papers

Azoles. Part 43:1 reactions of N-(phenylsulphonylmethyl)- and N-(phenylsulphinylmethyl)azoles with some nitroarenes

Treatment of nitroarenes with 1-(phenylsulphonylmethyl)azoles in the KOH/DMSO system at room temperature resulted usually in the cleavage of the phenylsulphonyl group, whereas the t-BuOK/DMF system at low temperature promotes to a greater extent oxidation of the σ-adducts. When 1-(phenylsulphinylmethyl)azoles were used for the reaction only elimination of the phenylsulphinyl group was observed. (C) 2000 Elsevier Science Ltd.

1-Chloromethyl-3,5-dimethylpyrazole hydrochloride. A useful synthetic intermediate

1-Chloromethyl-3,5-dimethylpyrazole hydrochloride readily undergoes nucleophilic displacement with O-, N-, or S-nucleophiles. 1-Phenylthiomethyl-3,5-dimethylpyrazole can be lithiated at the CH2 group and reacted with alkyl halides and carbonyl