122630-07-3Relevant academic research and scientific papers
SYNTHESIS OF (+/-) 11-DEOXYDAUNOMYCINONE AND 4-DEMETHOXY ANALOGUE BY SEQUENTIAL DIELS-ALDER CYCLOADDITIONS
Laugraud, Sylvain,Guingant, Andre,d'Angelo, Jean
, p. 83 - 86 (2007/10/02)
Diketones 10a, 10b, key intermediates in the syntheses of title compounds were prepared in five steps from naphtoquinones 2a and 2b (48 percent and 38 percent yields respectively), by sequential Diels-Alder cycloadditions.
A FORMAL TOTAL SYNTHESIS OF AKLAVINONE VIA A BLOCKED ANTHRAQUINONE TAUTOMER
Kraus, George A.,Walling, John A.
, p. 1873 - 1876 (2007/10/02)
An advanced intermediate in the Kishi synthesis of aklavinone was prepared.Juglone was converted into enone 4.Quinone 6 was then prepared from 4 by Michael addition and elimination of PhSOH and HCN.
