1226304-27-3Relevant articles and documents
Osmium catalyst for the borrowing hydrogen methodology: α-alkylation of arylacetonitriles and methyl ketones
Buil, Maria L.,Esteruelas, Miguel A.,Herrero, Juana,Izquierdo, Susana,Pastor, Isidro M.,Yus, Miguel
, p. 2072 - 2075 (2013)
Complex [Os(η6-p-cymene)(OH)(IPr)]OTf is an efficient catalyst precursor for the α-alkylation of arylacetonitriles and methyl ketones with alcohols, which works with turnover frequencies between 675 and 176 h-1 for nitriles and between 194 and 28 h-1 for ketones.