1226977-62-3Relevant academic research and scientific papers
A straightforward approach towards substituted morita-baylis-hillman products via hydrostannation of acetylenic ketones
Lakshmi, B. Vasantha,Kazmaier, Uli
experimental part, p. 407 - 410 (2010/04/28)
Regioselective molybdenum-catalyzed hydrostannations of acetylenic ketones give rise to allenoxystannanes, which can be subjected to subsequent aldol reactions. Because aldehydes are not affected under the reaction conditions used, the hydrostannation-aldol addition can be performed as a one-pot reaction, providing easy access to substituted Morita-Baylis-Hillman-type products in a highly stereoselective fashion. Georg Thieme Verlag Stuttgart New York.
