1226980-98-8

Basic information

• Product Name: (S)-4-[(1S,2R)-2-(tert-butyldiphenylsilyloxy)-1-hydroxyhexadecyl]oxazolidin-2-one
• Synonyms: (S)-4-[(1S,2R)-2-(tert-butyldiphenylsilyloxy)-1-hydroxyhexadecyl]oxazolidin-2-one
• CAS NO: 1226980-98-8
• Molecular Weight: 581.912
• Mol File: 1226980-98-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (S)-4-[(1S,2R)-2-(tert-butyldiphenylsilyloxy)-1-hydroxyhexadecyl]oxazolidin-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (S)-4-[(1S,2R)-2-(tert-butyldiphenylsilyloxy)-1-hydroxyhexadecyl]oxazolidin-2-one(1226980-98-8)
• EPA Substance Registry System: (S)-4-[(1S,2R)-2-(tert-butyldiphenylsilyloxy)-1-hydroxyhexadecyl]oxazolidin-2-one(1226980-98-8)

Safety Data

• Hazardous Substances Data: 1226980-98-8(Hazardous Substances Data)

Upstream product

• 1224436-76-3 (2S,3S,4R)-1-(tert-butyldiphenylsilyloxy)-2-[N-(tert-butyloxycarbonyl)amino]octadecan-3,4-diol 

Relevant articles and documents

Stereoselective divergent synthesis of four diastereomers of pachastrissamine (Jaspine B)

Figure presented A divergent short synthesis of four diastereomers of pachastrissamine was achieved. Natural pachastrissamine was synthesized through bis-tosylation of the common intermediate and cyclization. 2-epi- Pachastrissamine was obtained by monotosylation and spontaneous cyclization of d-ribo-phytosphingosine derivative. By use of regio- and stereospecific ring-opening reaction of the orthoester assisted by a Boc group as a key step, 3-epi- and 2,3-epi-pachastrissamines were synthesized. The three stereogenic centers of all the diastereomers were constructed by using Garners aldehyde as the sole chiral source.