1226996-74-2

Basic information

• Product Name: 1,6-anhydro-3-azido-3-deoxy-2-O-tosyl-β-D-galactopyranose
• Synonyms: 1,6-anhydro-3-azido-3-deoxy-2-O-tosyl-β-D-galactopyranose
• CAS NO: 1226996-74-2
• Molecular Weight: 341.345
• Mol File: 1226996-74-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1,6-anhydro-3-azido-3-deoxy-2-O-tosyl-β-D-galactopyranose(CAS DataBase Reference)
• NIST Chemistry Reference: 1,6-anhydro-3-azido-3-deoxy-2-O-tosyl-β-D-galactopyranose(1226996-74-2)
• EPA Substance Registry System: 1,6-anhydro-3-azido-3-deoxy-2-O-tosyl-β-D-galactopyranose(1226996-74-2)

Safety Data

• Hazardous Substances Data: 1226996-74-2(Hazardous Substances Data)

Upstream product

• 359772-53-5 1,6-Anhydro-3-azido-4-O-benzyl-3-deoxy-2-O-tosyl-β-D-galactopyranose 

Downstream Products

• 1226996-92-4 1,6-anhydro-3-azido-3,4-dideoxy-4-fluoro-2-O-tosyl-β-D-glucopyranose 
• 1226996-94-6 1,6-anhydro-3-azido-3,4-dideoxy-4-fluoro-2-O-tosyl-β-D-galactopyranose 

Relevant articles and documents

Synthesis of all configurational isomers of 1,6-anhydro-2,3,4-trideoxy-2,3- epimino-4-fluoro-β- d -hexopyranoses

We have prepared a full series of 1,6-anhydro-2,3,4-trideoxy-4-fluoro-2,3- epimino-β-d-hexopyranoses. The key step was the reaction of azido sulfonates possessing a free C-4 hydroxyl with DAST and subsequent LiAlH 4 reduction. Nucleophilic displacement of the hydroxyl activated by DAST proceeded without rearrangement and with moderate to good yields. A convenient synthesis of d-mannoepimine from a readily available 3-benzylamino derivative was also developed.