1227053-89-5Relevant articles and documents
[Ind2TiMe2]: A catalyst for the hydroaminomethylation of alkenes and styrenes
Kubiak, Raphael,Prochnow, Insa,Doye, Sven
supporting information; experimental part, p. 2626 - 2629 (2010/06/18)
(Chemical Equation Presentation) Metal-catalyzed hydroaminomethylations of styrenes, which take place by C-H bond activation, can be achieved in the presence of the catalyst [Ind2TiMe2] (Ind = η5-indenyl). Corresponding reactions of l-alkenes with N-methylanilines performed at temperatures between 80°C and 105°C usually take place with regioselectivities of better than 99:1 in favor of the branched product.