1227241-56-6Relevant articles and documents
The allylic nucleophilic substitution of Morita-Baylis-Hillman acetates with isocyanides: a facile synthesis of trisubstituted olefins
Yadav,Subba Reddy,Singh, Ashutosh Pratap,Majumder, Nilanjan
experimental part, p. 2291 - 2294 (2010/05/19)
Morita-Baylis-Hillman acetates undergo smooth allylic nucleophilic substitution (SN2′) with tosylmethyl isocyanide (TosMIC) in the presence of a catalytic amount of BF3·OEt2 under mild conditions to furnish trisubstituted olefins in high yields with (E)-stereoselectivity.