1227366-07-5Relevant academic research and scientific papers
Total syntheses of (+)-Fawcettimine and (+)-Lycoposerramine-B
Otsuka, Yasunari,Inagaki, Fuyuhiko,Mukai, Chisato
experimental part, p. 3420 - 3426 (2010/07/20)
The total synthesis of (+)-fawcettimine was completed in a highly stereoselective manner starting from the oxatricyclo[7.3.0.01,5] dodecanedione derivative. The crucial step in this total synthesis involves the efficient construction of the azonane framework by the intramolecular Mitsunobu reaction. Furthermore, the first total synthesis of (+)-lycoposerramine-B was also accomplished via the common synthetic intermediate.
