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Mechanistic Impact of Oxime Formation Accompanying 1,3-Dipolar Cycloadditions of Nitrile Oxides
Baran, Janusz,Mayr, Herbert
, p. 5012 - 5016 (2007/10/02)
Benzonitrile oxide (1a) reacts with 1,1,2,2,3,3-hexamethyl-4,5-bis(methylene)cyclopentane (5) to give a mixture of the 1,3-dipolar cycloaddition product 8 and the oxime 9.This reaction is 26 times slower than the corresponding reaction of 1a with 1,2-bis(
