122767-79-7Relevant academic research and scientific papers
Pahutoxin: Synthesis and Determination of Its Absolute Configuration
Yoshikawa, Masato,Sugimura, Takashi,Tai, Akira
, p. 37 - 40 (2007/10/02)
Optically pure pahutoxin and its antipode were synthesized from (S)- and (R)-3-hydroxyhexadecanoic acids, which were obtained by the enantio-differentiating hydrogenation of methyl 3-oxohexadecanoate over asymmetrically modified Raney nickel catalyst.By an optical correlation with synthetic materials, dextrorotatory natural pahutoxin was determined to be of (S)-configuration.
