122769-46-4Relevant academic research and scientific papers
Growth mechanism of thin films of a charge transfer complex, TTF-TCNQ, formed on alkali halide
Yase,Ara,Kawazu
, p. 185 - 190 (1994)
A charge transfer complex of tetrathiafulvalene and tetracyano-quinodimethane (TTF-TCNQ) is vacuum-deposited onto air-cleaved (001) planes of alkali halides, NaCl, KCl and KBr. The molecular orientation in thin films and surface morphology are characteriz
Wireless Electromechanical Readout of Chemical Information
Zhang, Lin,Gupta, Bhavana,Goudeau, Bertrand,Mano, Nicolas,Kuhn, Alexander
, p. 15501 - 15506 (2018)
Collecting electrochemical information concerning the presence of molecules in a solution is usually achieved by measuring current, potential, resistance, or impedance via connection to a power supply. Here, we suggest wireless electromechanical actuation
Electronically and ionically conductive gels of ionic liquids and charge-transfer tetrathiafulvalene-tetracyanoquinodimethane
Mei, Xiaoguang,Ouyang, Jianyong
, p. 10953 - 10961 (2011)
Electronically and ionically conductive gels were fabricated by mixing and mechanically grinding neutral tetrathiafulvalene (TTF) and tetracyanoquinodimethane (TCNQ) in ionic liquids (ILs) like 3-ethyl-1- methylimidazolium dicyanoamide (EMIDCA), 1-ethyl-3
Discrimination of alkyl and aromatic amine vapors using TTF-TCNQ based chemiresistive sensors
Wang, Chen,Wu, Na,Jacobs, Daniel L.,Xu, Miao,Yang, Xiaomei,Zang, Ling
supporting information, p. 1132 - 1135 (2017/01/29)
We report a chemiresistive sensor approach based on a TTF-TCNQ charge transfer material, which can real-time detect and distinguish the vapors of alkyl amine and aromatic amine species under ambient conditions, based on the dramatic difference in the kine
Switching of Transfer Characteristics of an Organic Field-Effect Transistor by Phase Transitions: Sensitive Response to Molecular Dynamics and Charge Fluctuation
Yokokura, Seiya,Takahashi, Yukihiro,Nonaka, Hiroki,Hasegawa, Hiroyuki,Harada, Jun,Inabe, Tamotsu,Kumai, Reiji,Okamoto, Hiroshi,Matsushita, Michio M.,Awaga, Kunio
, p. 4441 - 4449 (2015/06/30)
An organic field-effect transistor was fabricated using an anthracene-tetracyanoquinodimethane (AN-TCNQ) single-crystal charge-transfer (CT) complex as the semiconductor material. The CT complex showed molecular dynamics related to reorientational motion
Restoration of conductivity with TTF-TCNQ charge-transfer salts
Odom, Susan A.,Caruso, Mary M.,Finke, Aaron D.,Prokup, Alex M.,Ritchey, Joshua A.,Leonard, John H.,White, Scott R.,Sottos, Nancy R.,Moore, Jeffrey S.
experimental part, p. 1721 - 1727 (2011/11/13)
The formation of the conductive TTF-TCNQ (tetrathiafulvalenetetracyanoquinodimethane) charge-transfer salt via rupture of microencapsulated solutions of its individual components is reported. Solutions of TTF and TCNQ in various solvents are separately in
Electrochemical Behavior of Donor-Tetracyanoquinodimethane Electrodes in Aqueous Media
Jaeger, Calvin D.,Bard, Allen J.
, p. 5435 - 5442 (2007/10/02)
Electrodes prepared as compacted pellets from conductive donor-acceptor complexes of tetraquinodimethane (TCNQ) with several donors (D) (tetrathiotetracene, acridine, quinoline, N-methylphenazine, 2,2'- and 4,4'-bipyridine) were investigated in aqueous solutions.The results were compared to those of a previous investigation of TTF-TCNQ pellets (TTF = tetrathiafulvalene) and to results on single crystals of TTF-TCNQ reported here.The electrodes are stable over a potential region in which they could be employed as inert electrodes.The potential limits depended upon the stabilization gained upon complexation and the relative electrode potentials of the constituent compounds.Upon exceeding the potential limits of stability of the electrode, the electrode was reduced or oxidized.Subsequent voltammograms showed peaks attributable to insoluble compounds formed on the electrode surface.The potentials observed for the redox processes could be correlated to the degree of charge transfer, ρ, as well as gas-transfer ionization potentials and electron affinities.
