1227695-39-7Relevant articles and documents
N,N-Dimethylpyridin-4-Amine mediated protocol for cyanoethoxycarbonylation of aldehydes under solvent-free conditions
Khan, Noor-Ul H.,Agrawal, Santosh,Kureshy, Rukhsana I.,Bera, Prasanta K.,Abdi, Sayed H.R.,Bajaj, Hari C.
, p. 255 - 260 (2010)
N,N-Dimethylpyridin-4-amine(DAMP)(10 mol%) was successfully employed as catalyst for cyanoethoxycarbonylation of aromatic and aliphatic aldehydes at room temperature under solvent free condition to give corresponding ethylcyanocarbonates in excellent isol
N-heterocyclic carbene catalyzed cyanation reaction of carbonyl compounds with ethyl cyanoformate and acetyl cyanide
Zhang, Jie,Du, Guangfen,Xu, Yueke,He, Lin,Dai, Bin
supporting information; experimental part, p. 7153 - 7156 (2012/01/05)
N-heterocyclic carbene (NHC) has been employed as an efficient catalyst for cyanation reaction of carbonyl compounds. Under catalysis of 1 mol % NHCs, various aldehydes and 2,2,2-trifluoroacetophenone coupled with ethyl cyanoformate in THF to provide cyanohydrins ethyl carbonates in excellent yields. While in the presence of 10 mol % catalyst, different types of aldehydes and 2,2,2-trifluoroacetophenone reacted with acetyl cyanide in dichloroethane to give acylated cyanohydrins in moderate to high yields.