122775-25-1Relevant academic research and scientific papers
Regioselective hydroalumination of allenes and their synthetic application
Nagahara,Maruoka,Yamamoto
, p. 3783 - 3789 (2007/10/02)
The hydroalumination of a terminal allene, 1,2-nonadiene, with LiAlH4 in THF using [TiCl2(Cp)2], TiCl4, TiCl3, ZrCl4, and [ZrCl2 (CP)2] catalyst afforded a wide variet
Organoborane-Catalyzed Hydroalumination of Terminal Allenes
Nagahara, Shigeru,Maruoka, Keiji,Doi, Yoshiharu,Yamamoto, Hisashi
, p. 1595 - 1598 (2007/10/02)
Organoborane-catalyzed hydroalumination of terminal allenes with dichloroaluminum hydride gives rise to the corresponding allylaluminum compounds under mild conditions with high regioselectivity.
Preparation of 1-substituted 1-vinylcycloalkanes from 3,3-tetra- and 3,3-penta-methyleneallylboranes
Bubnov, Yu. N.,Zheludeva, V. I.,Ignatenko, A. V.
, p. 151 - 158 (2007/10/02)
The boranes I and II, obtained by hydroboration of 1,1-tetra- and 1,1-penta-methyleneallenes with 9-BBN, were used as key reactants in the synthesis of a series of unsaturated gem-substituted carbinols (VIIa-VIIg, Xa-Xc, and XII), as well as 1,1-divinylcy
The Mechanism of the Protodesilylation of Allylsilanes which are Disubstituted on C-3
Fleming, Ian,Marchi, Decio,Patel, Shailesh K.
, p. 2518 - 2519 (2007/10/02)
3,3-Dialkylallylsilanes react with protons by two delicately balanced mechanisms.The allylsilane (5) reacts directly by protonation on C-3 of the allyl group, followed by loss of the silyl group.On the other hand, the allylsilanes (7) and (10) react, at l
