1227798-64-2Relevant academic research and scientific papers
Rhodium-catalyzed asymmetric arylation of N -(tert -butanesulfinyl)imines with sodium tetraarylborates
Reddy, Leleti Rajender,Gupta, Aditya P.,Villhauer, Eric,Liu, Yugang
, p. 1095 - 1100 (2012/03/12)
A diastereoselective rhodium-catalyzed arylation of N-(tert-butanesulfinyl) imines with sodium tetraarylborates is described. This method is general for constructing various chiral α-branched amines and 2-substituted pyrrolidines with high diastereoselectivity. A practical asymmetric approach to access chiral amines has been developed involving the use of air-stable Rh catalysts and reagents and in the absence of an external ligand.
Asymmetric synthesis of 2-arylpyrrolidines starting from γ-chloro N-(tert-butanesulfinyl)ketimines
Leemans, Erika,Mangelinckx, Sven,De Kimpe, Norbert
scheme or table, p. 3122 - 3124 (2010/09/04)
The enantioselective reductive cyclization of γ-chloro N-(tert-butanesulfinyl)ketimines towards the short and efficient synthesis of (S)- and (R)-2-arylpyrrolidines (ee >99%) is described for the first time by treatment with LiBEt3H and subsequ
