1228016-71-4Relevant academic research and scientific papers
Nitrone cycloaddition to quinones: A novel strategy for the synthesis of benzisoxazolidenes
Paul, Rony Rajan,Varghese, Vimal,Beneesh,Sinu,Suresh,Anabha
experimental part, p. 396 - 399 (2010/06/16)
(Chemical Equation Presented) 1,3-Dipolar cycloaddition reaction involving nitrones and benzoquinones resulting in the formation of benzisoxazolidene is described. As the nitrone is selectively added to carbon-carbon double bond of the benzoquinone, the quinone-nitrone reaction is considered as a special case among quinone-1,3-dipole cycloaddition reactions. Molecular orbital calculation was performed to examine the electronic effects involved in the regioselectivity of the reaction.
