122822-21-3

Basic information

• Product Name: (2R,3S,4S,5R/S)-5-O-benzyl-4-methyl-2-O-(tert-butyldimethylsilyl)dec-6-yne-1,2,3,5-tetrol
• CAS NO: 122822-21-3
• Molecular Weight: 420.665
• Mol File: 122822-21-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (2R,3S,4S,5R/S)-5-O-benzyl-4-methyl-2-O-(tert-butyldimethylsilyl)dec-6-yne-1,2,3,5-tetrol(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,3S,4S,5R/S)-5-O-benzyl-4-methyl-2-O-(tert-butyldimethylsilyl)dec-6-yne-1,2,3,5-tetrol(122822-21-3)
• EPA Substance Registry System: (2R,3S,4S,5R/S)-5-O-benzyl-4-methyl-2-O-(tert-butyldimethylsilyl)dec-6-yne-1,2,3,5-tetrol(122822-21-3)

Safety Data

• Hazardous Substances Data: 122822-21-3(Hazardous Substances Data)

Upstream product

• 77102-19-3 dimethylaluminum 1-pentynide 
• 115983-66-9 benzyl 2-deoxy-2-C-methyl-4-O-(tert-butyldimethylsilyl)-α-D-arabinopyranoside 

Relevant articles and documents

Organoaluminum-Induced Opening of the Pyranosidic Ring of Benzyl 2-Deoxy-2-C-methylpentopyranosides

Benzyl 2-deoxy-2-C-methylpentopyranosides ring open via attack at the anomeric carbon by the nucleophilic part of organoaluminum reagents (Me2AlR) to give chiral, partially protected, branched 1,2,3,5-tetrol derivatives 13-32.The reaction represents a direct chain extension of the glycosides at C-1.