1228296-10-3

Basic information

• Product Name: 3-(1-methoxybut-3-enyl)phenol
• Synonyms: 3-(1-methoxybut-3-enyl)phenol
• CAS NO: 1228296-10-3
• Molecular Weight: 178.231
• Mol File: 1228296-10-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 3-(1-methoxybut-3-enyl)phenol(CAS DataBase Reference)
• NIST Chemistry Reference: 3-(1-methoxybut-3-enyl)phenol(1228296-10-3)
• EPA Substance Registry System: 3-(1-methoxybut-3-enyl)phenol(1228296-10-3)

Safety Data

• Hazardous Substances Data: 1228296-10-3(Hazardous Substances Data)

Upstream product

• 24396-25-6 m-hydroxybenzaldehyde dimethyl acetal 
• 72824-04-5 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 

Relevant articles and documents

Unusual carbon-carbon bond formations between allylboronates and acetals or ketals catalyzed by a peculiar indium(I) lewis acid

InIOTf has been uncovered as an effective Lewis acid catalyst for unprecedented nucleophilic substitution of acetals or ketals with allylboronates. A transmetalative SN1 mechanism is proposed in which a single InI center acts as a dual catalyst to activate both reagents sequentially. Contrary to the classic γ-selectivity of allylsilanes (Hosomi-Sakurai reaction), this InI-catalyzed borono variant displays distinct α-selectivity. Substrate scope and functional group tolerance proved to be excellent.