122835-22-7Relevant academic research and scientific papers
Zinc-promoted cyclization of tosylhydrazones and 2-(dimethylamino)malononitrile: An efficient strategy for the synthesis of substituted 1-tosyl-1: H -pyrazoles
Zhang, Bang-Hong,Lei, Lin-Sheng,Liu, Si-Zhan,Mou, Xue-Qing,Liu, Wei-Ting,Wang, Shao-Hua,Wang, Jie,Bao, Wen,Zhang, Kun
, p. 8545 - 8548 (2017/08/04)
A Zn(OTf)2-promoted cyclization reaction of tosylhydrazones with 2-(dimethylamino)malononitrile has been successfully developed providing an efficient strategy for the synthesis of substituted 1-tosyl-1H-pyrazoles.
(1)BENZOPYRANO(4,3-c)PYRAZOLES BY INTRAMOLECULAR NITRILE IMINE ADDITION TO ACETYLENES
Janietz, Dietmar,Rudorf, Wolf-Dieter
, p. 1661 - 1666 (2007/10/02)
2-Alkynyloxy-benzaldehydes 1 are obtained by alkylation of the corresponding salicylaldehydes either with p-toluenesulfonic acid propargylester or 1-acetoxy-4-chloro-but-2-yne.The aldehydes 1 are converted into the hydrazones 2 by reaction with p-toluenes
