1228390-57-5

Basic information

• Product Name: rhodium(III)(5,10,15,20-tetratolylporphyrinato dianion)ⁿBu
• Synonyms: rhodium(III)(5,10,15,20-tetratolylporphyrinato dianion)ⁿBu
• CAS NO: 1228390-57-5
• Molecular Weight: 828.862
• Mol File: 1228390-57-5.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: rhodium(III)(5,10,15,20-tetratolylporphyrinato dianion)ⁿBu(CAS DataBase Reference)
• NIST Chemistry Reference: rhodium(III)(5,10,15,20-tetratolylporphyrinato dianion)ⁿBu(1228390-57-5)
• EPA Substance Registry System: rhodium(III)(5,10,15,20-tetratolylporphyrinato dianion)ⁿBu(1228390-57-5)

Safety Data

• Hazardous Substances Data: 1228390-57-5(Hazardous Substances Data)

Upstream product

• 542-69-8 1-iodo-butane 
• 205259-72-9 rhodium(III) tetrakis(4-tolyl)porphyrin chloride 
• 102-82-9 tributyl-amine 
• 103533-57-9 [rhodium(II)(5,10,15,20-tetratolylporphyrin)]2 
• 663189-71-7 Rh(5,10,15,20-tetratolylporphyrin) 
• 103562-44-3 (5,10,15,20-tetrakis-4-tolylporphyrinato)rhodium(III) hydride 
• 71-36-3 butan-1-ol 

Relevant articles and documents

Facile Aerobic Alkylation of Rhodium Porphyrins with Alkyl Halides

Alkylation of rhodium porphyrins was achieved in moderate to high yields in the presence of air and water. With this facile alkylation method, various alkyl RhIII(por) species, including those with tertiary alkyl, were synthesized. Mechanistic

Carbon-nitrogen bond activation of amines by rhodium(III) porphyrin complexes

Carbon-nitrogen bond activation of amines by rhodium porphyrin chloride has been achieved to give rhodium porphyrin alkyl complexes. Rhodium porphyrin hydride and rhodium porphyrin dimer were proposed as the intermediates in cleaving the C-N bond.