122844-89-7

Upstream product

• 17873-08-4 (phenylsulfanylmethyl)trimethylsilane 
• 122844-86-4 3-(tert-Butyl-dimethyl-silanyloxy)-5-(2-dimethoxymethyl-6-methoxy-benzyl)-2,6,6-trimethyl-cyclohex-2-enone 
• 122844-96-6 3-(2-Dimethoxymethyl-6-methoxy-benzyl)-2,2-dimethyl-5-oxo-heptanoic acid ethyl ester 
• 122844-97-7 5-(2-Dimethoxymethyl-6-methoxy-benzyl)-2,4,4-trimethyl-cyclohexane-1,3-dione 
• 122844-94-4 Acetic acid (E)-4-(2-dimethoxymethyl-6-methoxy-phenyl)-1-ethyl-but-2-enyl ester 
• 122844-95-5 (E)-6-(2-Dimethoxymethyl-6-methoxy-phenyl)-hex-4-en-3-one 
• 122844-93-3 6-Bromo-4-hexen-3-yl acetate 
• 59276-28-7 m-anisaldehyde dimethyl acetal 
• 122844-87-5 tert-Butyl-{5-(2-dimethoxymethyl-6-methoxy-benzyl)-2,4,4-trimethyl-3-[1-phenylsulfanyl-meth-(Z)-ylidene]-cyclohex-1-enyloxy}-dimethyl-silane 

Relevant academic research and scientific papers

Synthetic studies on taxane carbon framework. A highly efficient eight-membered ring cyclization with complete stereocontrol

Cyclization reaction of 5-[2-(dimethoxymethyl)-6-methoxy]benzyl-2,4,4-trimethyl-3-(trimethyls ilylmethyl)cyclohexenone 2 and 5-[2-(dimethoxymethyl)-6-methoxy]benzyl-2,6,6-trimethyl-3-(siloxy)-1- methylenecyclohex-2-ene 9 gave the corresponding endo tricar