122845-02-7Relevant academic research and scientific papers
Cross-Dehydrogenative C-H Amination of Indoles under Aerobic Photo-oxidative Conditions
Yamaguchi, Tomoaki,Yamaguchi, Eiji,Itoh, Akichika
, p. 1282 - 1285 (2017)
A novel cross-dehydrogenative C(sp2)-H amination catalyzed by an organic photocatalyst is reported. The reaction is mediated by 2-tert-butylanthraquinone as a photocatalyst, harmless visible light, and aerobic oxygen as the sole oxidant without a transition-metal catalyst and or external oxidant.
Effect of N-Chloro Structure and 1-Substituent on ?-Substitution (Addition - Elimination) in Pyrroles
Rosa, Michael De,Nieto, Gustavo Cabrera,Gago, Fernando Ferrer
, p. 5347 - 5350 (2007/10/02)
1-Methylpyrrole was reacted with a number of different types of N-chloro derivatives, and ?-substitution was observed only with N-chloroimides.It is proposed that there is qualitative relationship between the pKa of the N-chloro precursor and t
