1228632-34-5

Usage

Molecular structure

The compound consists of a phenanthroimidazole core with a phenyl and dioxaborolane group attached.

Aromatic and boron-containing functional groups

The compound contains multiple aromatic rings and a boron-containing functional group, which contribute to its unique properties.

Application in materials science

Due to its unique electronic and photophysical properties, as well as high photoluminescence efficiency, the compound has significant potential for use in the development of OLEDs (organic light-emitting diodes) and other electronic devices.

Intricate structure

The compound's complex structure makes it a subject of interest for researchers in the fields of organic chemistry and materials science.

High photoluminescence efficiency

The compound exhibits high photoluminescence efficiency, which is crucial for its potential applications in electronic devices.

Electronic properties

The unique electronic properties of the compound, such as its ability to emit light when an electric current is applied, make it suitable for use in various electronic devices, including OLEDs.

Photophysical properties

The compound's photophysical properties, including its ability to absorb and emit light, contribute to its potential applications in electronic devices and materials science.

Upstream product

• 61676-62-8 2-Isopropoxy-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 1147081-43-3 2-(4-bromophenyl)-1-phenyl-1H-phenanthro- [9,10-d]imidazole 
• 84-11-7 9,10-phenanthrenequinone 
• 62-53-3 aniline 
• 1122-91-4 4-bromo-benzaldehyde 
• 104-88-1 4-chlorobenzaldehyde 
• 36951-28-7 2-(4-chloro-phenyl)-1-phenyl-1H-phenanthro[9,10-d]imidazole 
• 73183-34-3 bis(pinacol)diborane 

Downstream Products

• 1197177-29-9 1-phenyl-2-(4'-(triphenylsilyl)-(1,1'-biphenyl)-4-yl)-1H-phenanthro[9,10-d]imidazole 
• 1579955-06-8 2-(4’-((4-(9H-carbazol-9-yl)phenyl)diphenylsilyl)-(1,1’-biphenyl)-4-yl)-1-phenyl-1H-phenanthro[9,10-d]imidazole 
• 1579955-07-9 2-(4’-((4-(9H-[3,9’-bicarbazol]-9-yl)phenyl)diphenylsilyl)-(1,1’-biphenyl)-4-yl)-1-phenyl-1H-phenanthro[9,10-d]imidazole 
• 1197175-44-2 2-(4-(10-(naphthalen-2-yl)anthracen-9-yl)phenyl)-1-phenyl-1H-phenanthro[9,10-d]imidazole 
• 1621007-86-0 1-phenyl-2-(4-(1,2,2-triphenylvinyl)phenyl)-1H-phenanthro[9,10-d]imidazole 
• 1619222-83-1 1-phenyl-2-(4’-(1,2,2-triphenylvinyl)-[1,1’-biphenyl]-4-yl)-1H-phenanthro[9,10-d]imidazole 

Relevant academic research and scientific papers

Method for separating halogenated impurities from organic light-emitting material

The invention discloses a method for separating halogenated impurities from an organic light-emitting material. The method comprises the steps: carrying out Suzuki reaction by utilizing halide, coupling with a boric acid ester raw material with an amino-containing side chain, and converting halogenated impurities into a compound containing an amino polar group; and furthermore, ionizing the compound containing the amino polar group by acid, so as to dissolve the compound in strong polar solvents such as alcohol and the like to realize remarkable solubility difference with an organic light-emitting material, and thus obtaining material purification. According to the method, the halogenated impurities in the organic light-emitting material are converted into the compound containing the amino polar groups, efficient separation can be achieved by well utilizing the solubility difference between the compound containing the amino polar groups and the organic light-emitting material, and then the purity of the organic light-emitting material is improved. According to the method, the halogenated impurities are removed in a targeted manner, the negative influence of halogen on an organic light-emitting device can be eliminated, the device efficiency is greatly improved, and the service life is greatly prolonged.

Blue fluorescent material with high exciton utilization rate and preparation and application thereof

The invention belongs to the technical field of organic photoelectric materials, and discloses a blue fluorescent material with high exciton utilization rate as well as preparation and application thereof. The blue fluorescent material is one or more of a formula I and a formula II. The invention also discloses a preparation method of the blue fluorescent material. The material provided by the invention is a blue fluorescent material, can form hybrid local charge transfer state (HLCT) luminescence, realizes a high-energy triplet state to singlet state reverse system crossing process, and improves the exciton utilization rate. Meanwhile, the blue fluorescent material is high in fluorescence quantum yield, high in carrier mobility and good in stability. The material provided by the inventionhas good performance in organic light-emitting devices. The blue fluorescent material disclosed by the invention is used for preparing an organic light-emitting device.

Green light compound based on dibenzophenazine, preparation method and device thereof

The invention belongs to the technical field of photoelectric display devices, and particularly relates to a green light compound based on dibenzophenazine, a preparation method and a device thereof. The invention provides the green light compound based o

High-performance non-doped blue OLEDs based on 1,2,4-triazole-phenanthroimidazole derivatives with negligible efficiency roll-off

Triazole and phenanthroimidazole moieties are commonly used to construct efficient blue-emitting materials as acceptors and donors, respectively. Benefitting from the D-A coupling of the two moieties, two novel bipolar blue emitters,TAZ-PPIand4NTAZ-PPI, w

Pyridoimidazole derivatives as well as preparation method and application thereof

The invention discloses pyridoimidazole derivatives as well as a preparation method and application thereof. The pyridoimidazole derivatives with two D-pi-A structures are synthesized on the basis that pyridoimidazole serves as an electron acceptor system by means of the electron donating property of phenanthroimidazole/diphenylamine. The pyridoimidazole derivatives can serve as photoinitiators, and the two photoinitiators both have longer conjugated chain lengths, so that the photon absorption cross section is increased, the photoinitiators can initiate polymerization reaction at the wavelength of 365 nm, have higher polymerization efficiency, and can be widely applied to the field of ultraviolet curing.

Aromatic compound containing tetraphenyl ethylene structure and preparation method and application thereof

The invention provides an aromatic compound containing a tetraphenylethylene structure and a preparation method and application thereof, belonging to the technical field of fluorescence sensing. The preparation method of the aromatic compound containing the tetraphenylethylene structure comprises the following steps: reacting a halogenated aromatic ring with borate under anhydrous and anaerobic conditions to obtain an aryl borate intermediate; and carrying out a SUZUKI reaction on the aryl borate intermediate and halogenated tetraphenyl ethylene to obtain the aromatic compound containing the tetraphenylethylene structure. The aromatic compound containing the tetraphenyl ethylene structure provided by the invention has a relatively large conjugated structure and a wide charge delocalizationrange, and the unique three-dimensional configuration of the aromatic compound is beneficial for obtaining a good aggregation structure, so the aromatic compound has good application prospects in thefields of sensing technologies and detection functions, is high in practicability and shows relatively high popularization and application values.

Organic light-emitting molecule and application thereof in organic light-emitting diode (by machine translation)

The invention discloses an organic light-emitting molecule and application thereof in an organic light-emitting diode. The molecule has the characteristics of wide band gap, high fluorescence quantum yield, high electron mobility, high hole mobility, high exciton utilization rate and the like. The molecules have an asymmetric structure, molecule aggregation can be inhibited, and exciton quenching is reduced. In addition, it is possible to adjust its emission spectrum by changing the connection site of the two units. The organic electroluminescent device can be used for preparing high-efficiency blue-light organic electroluminescent devices with different emission wavelengths. (by machine translation)

D-A type light-emitting small molecule containing acridine and phenanthroimidazole and application thereof in electroluminescent device

The invention discloses an electron donor-acceptor D-A type light-emitting small molecule containing acridine and phenanthroimidazole and application thereof in an electroluminescent device. An acridine electron donor unit and a phenanthroimidazole electr

S,S-dioxo-dibenzothiophene and phenanthroimidazole based small molecule and application thereof in electroluminescent devices

The invention discloses an S,S-dioxo-dibenzothiophene and phenanthroimidazole based small molecule and application thereof in electroluminescent devices. Phenanthroimidazole is used as a donor unit, S,S-dioxo-dibenzothiophene is used as an acceptor unit, and a novel donor-acceptor type blue fluorescent molecule is constructed. The molecule has the characteristics of S,S-dioxo-dibenzothiophene suchas wide band gap, high fluorescence quantum yield, strong electron affinity, high electron mobility, and also has the characteristics of phenanthroimidazole such as large conjugate rigid structure, bipolar transmission, and the like. The molecule has an asymmetric structure, and can inhibit molecular aggregation and reduce exciton quenching. In addition, the emission spectrum can be adjusted by changing the connection sites of the two units. The small molecule can be used for preparing high-efficiency blue light organic electroluminescent devices with different emission wavelengths.

Highly efficient non-doped blue fluorescent OLEDs with low efficiency roll-off based on hybridized local and charge transfer excited state emitters

Designing a donor-acceptor (D-A) molecule with a hybridized local and charge transfer (HLCT) excited state is a very effective strategy for producing an organic light-emitting diode (OLED) with a high exciton utilization efficiency and external quantum efficiency. Herein, a novel twisting D-π-A fluorescent molecule (triphenylamine-anthracene-phenanthroimidazole; TPAAnPI) is designed and synthesized. The excited state properties of the TPAAnPI investigated through photophysical experiments and density functional theory (DFT) analysis reveal that its fluorescence is due to the HLCT excited state. The optimized non-doped blue OLED using TPAAnPI as a light-emitting layer exhibits a novel blue emission with an electroluminescence (EL) peak at 470 nm, corresponding to the Commission International de L'Eclairage (CIE) coordinates of (0.15, 0.22). A fabricated device termed Device II exhibits a maximum current efficiency of 18.09 cd A?1, power efficiency of 12.35 lm W?1, luminescence of ≈29 900 cd cm?2, and external quantum efficiency (EQE) of 11.47%, corresponding to a high exciton utilization efficiency of 91%. Its EQE remains as high as 9.70% at a luminescence of 1000 cd m?2with a low efficiency roll-off of 15%. These results are among the best for HLCT blue-emitting materials involved in non-doped blue fluorescent OLEDs. The performance of Device II highlights a great industrial application potential for the TPAAnPI molecule.