1228685-47-9Relevant academic research and scientific papers
I -PrI acceleration of Negishi cross-coupling reactions
Kienle, Marcel,Knochel, Paul
, p. 2702 - 2705 (2010)
(Figure presented) The Negishi cross-coupling of arylzinc reagents with various bromoanilines is accelerated by the presence of i-PrI (1 equiv) and furnished the expected biaryls within 5-12 min reaction time at 25 °C. Arylzinc reagents can also be cross-coupled under these conditions with a range of aryl bromides bearing an enolizable ester or acidic benzylic protons.
