1228689-10-8

Basic information

• Product Name: C₂₆H₃₆O₄SSi
• Synonyms: C₂₆H₃₆O₄SSi
• CAS NO: 1228689-10-8
• Molecular Weight: 472.721
• Mol File: 1228689-10-8.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₂₆H₃₆O₄SSi(CAS DataBase Reference)
• NIST Chemistry Reference: C₂₆H₃₆O₄SSi(1228689-10-8)
• EPA Substance Registry System: C₂₆H₃₆O₄SSi(1228689-10-8)

Safety Data

• Hazardous Substances Data: 1228689-10-8(Hazardous Substances Data)

Upstream product

• 1779-54-0 methylthiomethyl(triphenyl)phosphonium chloride 
• 96690-02-7 5-O-(tert-butyldiphenylsilyl)-2,3-O-isopropylidene-D-ribofuranose 

Downstream Products

• 1228689-19-7 C₂₇H₃₈O₅SSi 

Relevant articles and documents

Anodic coupling reactions and the synthesis of C-glycosides

A convenient, two-step procedure has been developed for converting sugar derivatives into C-glycosides containing a masked aldehyde functional group. The chemistry takes advantage of an anodic coupling reaction between an electron-rich olefin and an alcohol. The sequence works for the formation of both furanose and pyranose derivatives if less polarized vinyl sulfide derived radical cation intermediates are used. With more polarized enol ether derived radical cations, the cyclizations work best for the formation of furanose derivatives where the rate of five-membered ring formation precludes elimination reactions triggered by the radical cation.