1228813-92-0

Basic information

• Product Name: C₆F₄IN
• CAS NO: 1228813-92-0
• Molecular Weight: 288.971
• Mol File: 1228813-92-0.mol

Chemical Properties

• CAS DataBase Reference: C₆F₄IN(CAS DataBase Reference)
• NIST Chemistry Reference: C₆F₄IN(1228813-92-0)
• EPA Substance Registry System: C₆F₄IN(1228813-92-0)

Safety Data

• Hazardous Substances Data: 1228813-92-0(Hazardous Substances Data)

Upstream product

• 1228813-90-8 2-iodo-3,4,5,6-tetrafluorophenylazide 

Relevant articles and documents

3,4,5,6-tetrafluorophenylnitren-2-yl: A ground-state quartet triradical

The photochemistry of 2iodo-3,4,5,6-tetrafluorophenyl azide (7d) has been investigated in argon and neon matrices at 4 K, and the products characterized by IR and EPR spectroscopy. The primary photochemical step is loss of a nitrogen molecule and formation of phenyl nitrene 1d. Further irradiation with UV or visible light results in mixtures of Id with azirine 5d′ , ketenimine 6d′, nitreno radical 2d, and azirinyl radical 9. The relative amounts of these products strongly depend on the matrix and on the irradiation conditions. Nitreno radical 2d with a quartet ground state was characterized by EPR spectroscopy. Electronic structure calculations in combination with the experimental results allow for a detailed understanding of the properties of this unusual new type of organic high-spin molecules.