122887-07-4Relevant academic research and scientific papers
OXIDATIVE RING OPENING OF 2-PYRAZOLINES. APPLICATION TO LACTAMISATION AND FORMYLATION OF 1,3-6H-THIAZINES.
Tuloup, R.,Danion-Bougot, R.,Danion, D.,Pradere, J.P.
, p. 6249 - 6252 (1988)
Benzeneseleninic anhydride allows oxidative ring opening of 2-pyrazolines to α,β-unsaturated carbonyl compounds.Thus, a pyrazoline ring may be used as a masking, a stereodirecting and a latent formyl group in the synthesis of 7-amino 4-formyl cephem from 1,3-6H-thiazine.
