1228873-50-4Relevant academic research and scientific papers
1,3-Diphosphorus ylide cyclopentadienylium salts: Synthesis, structures, and application in coupling reactions
Xu, Chen,Wang, Zhi-Qiang,Li, Zhen,Wang, Wei-Zhou,Hao, Xin-Qi,Fu, Wei-Jun,Gong, Jun-Fang,Ji, Bao-Ming,Song, Mao-Ping
, p. 798 - 801 (2012)
The 1,3-diphosphorus ylide cyclopentadienylium salts (C5H 3)(PPh3)2I (1) and (C5H 3)[P(4-CH3-Ph)3]2I (2) have been prepared from the reaction of 1,1′-dichloromercurioferrocene with Pd(PPh3)4 and with Pd[P(4-CH3-Ph) 3]4, respectively. The molecular structure of 1 has been determined by X-ray diffraction analyses. The Pd(OAc)2/1 or 2/K tOBu system is highly efficient for the coupling reactions of aryl chlorides at room temperature.
