1229029-89-3Relevant academic research and scientific papers
Stereoselective syntheses of four diastereomers of 3,9,12- trihydroxycalamenene via a benzobicyclo[3.3.1] intermediate
Sun, Yongquan,Yu, Binxun,Wang, Xiaolei,Tang, Shibing,She, Xuegong,Pan, Xinfu
, p. 4224 - 4229 (2010)
The highly stereoselective syntheses of four diastereomers of natural 3,9,12-trihydroxycalamenene are described. The syntheses highlight the utility of an unusual framework of benzobicyclo[3.3.1] lactones, which were accomplished via an intramolecular Friedel-Crafts-type Michael addition of α,β-unsaturated lactones.
