122913-35-3Relevant academic research and scientific papers
HYPERVALENT ORGANOIODINE REAGENTS IN THE β-FRAGMENTATION OF BICYCLIC CARBINOLAMIDES LEADING TO IMIDES
Hernandez, R.,Marrero, J. J.,Melian, D.,Suarez, E.
, p. 6661 - 6664 (1988)
A mild and convenient method for the synthesis of 3,4-substituted cyclic imides by photolysis of bicyclic - and -carbinolamides in the presence of (diacetoxyiodo)-benzene and iodine is described.
RADICAL β-FRAGMENTATION OF BICYCLOCARBINOLAMIDES: SYNTHESIS OF FIVE- AND EIGHT-MEMBERED CYCLIC IMIDES
Hernandez, Rosendo,Melian, Daniel,Prange, Thierry,Suarez, Ernesto
, p. 439 - 454 (2007/10/02)
The influence of 4-alkyl or 4-aryl substituents in the regioselectivity of the β-fragmentation of carbinolamidyl radicals generated from the corresponding carbinolamides (7-13) by irradiation with visible light in the presence of (diacetoxyiodo)benzene an
A Selenurane Derivative Promotes β-Fragmentation of Carbinolamides Leading to Cyclic Imides
Dorta, Rosa L.,Francisco, Cosme G.,Suarez, Ernesto
, p. 1083 - 1086 (2007/10/02)
The alkoxy radical intermediates generated by reaction of carbinolamides with diphenylselenium hydroxyacetate (1) in the presence of iodine and under irradiation with visible light undergo β-fragmentation to afford 3,4-substituted cyclic imides in good yields.
