1229231-47-3

Basic information

• Product Name: (R)-(+)-3-methyl-4-(p-tolyl)but-3-en-2-ol
• Synonyms: (R)-(+)-3-methyl-4-(p-tolyl)but-3-en-2-ol
• CAS NO: 1229231-47-3
• Molecular Weight: 176.258
• Mol File: 1229231-47-3.mol

Chemical Properties

• CAS DataBase Reference: (R)-(+)-3-methyl-4-(p-tolyl)but-3-en-2-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (R)-(+)-3-methyl-4-(p-tolyl)but-3-en-2-ol(1229231-47-3)
• EPA Substance Registry System: (R)-(+)-3-methyl-4-(p-tolyl)but-3-en-2-ol(1229231-47-3)

Safety Data

• Hazardous Substances Data: 1229231-47-3(Hazardous Substances Data)

Upstream product

• 69390-18-7 (E)-3-methyl-4-(4-methylphenyl)-3-buten-2-one 

Relevant articles and documents

Asymmetric Magnesium-Catalyzed Hydroboration by Metal-Ligand Cooperative Catalysis

Asymmetric catalysis with readily available, cheap, and non-toxic alkaline earth metal catalysts represents a sustainable alternative to conventional synthesis methodologies. In this context, we describe the development of a first MgII-catalyzed enantioselective hydroboration providing the products with excellent yields and enantioselectivities. NMR spectroscopy studies and DFT calculations provide insights into the reaction mechanism and the origin of the enantioselectivity which can be explained by a metal-ligand cooperative catalysis pathway involving a non-innocent ligand.

CuH-catalyzed enantioselective 1,2-reductions of α,β-unsaturated ketones

The first study on a general technology for arriving at valued nonracemic allylic alcohols using asymmetric ligand-accelerated catalysis by copper hydride is described.