1229248-02-5

Basic information

• Product Name: N-2,3,4-trifluorophenyl-3,5-di-tert-butylsalicylaldimine
• Synonyms: N-2,3,4-trifluorophenyl-3,5-di-tert-butylsalicylaldimine
• CAS NO: 1229248-02-5
• Molecular Weight: 363.423
• Mol File: 1229248-02-5.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: N-2,3,4-trifluorophenyl-3,5-di-tert-butylsalicylaldimine(CAS DataBase Reference)
• NIST Chemistry Reference: N-2,3,4-trifluorophenyl-3,5-di-tert-butylsalicylaldimine(1229248-02-5)
• EPA Substance Registry System: N-2,3,4-trifluorophenyl-3,5-di-tert-butylsalicylaldimine(1229248-02-5)

Safety Data

• Hazardous Substances Data: 1229248-02-5(Hazardous Substances Data)

Upstream product

• 37942-07-7 3,5-di-tert-butyl-2-hydroxybenzaldehyde 
• 3862-73-5 2,3,4-trifluoroaniline 

Downstream Products

• 1229248-03-6 C₄₂H₄₆CuF₆N₂O₂ 
• 1229248-04-7 C₄₂H₄₆F₆N₂O₂Pd 

Relevant articles and documents

Synthesis, structural, spectroscopic and reactivity properties of a new N-2,3,4-trifluorophenyl-3,5-di-tert-butylsalicylaldimine ligand and its Cu(II) and Pd(II) complexes

A new N-2,3,4-trifluorophenyl-3,5-di-tert-butylsalicylaldimine (1) complexes with Cu(II) (2) and Pd(II) (3) have been synthesized and characterized by X-ray crystallography, UV-Vis, IR, 1H NMR and EPR spectroscopic techniques. The X-ray crystal structure of complex 2 reveals tetrahedrally distorted square-planar coordination geometry around Cu(II). The UV/Vis and EPR results indicate that the solid state geometry of 2 remains unchanged in solutions. Chemical oxidation of 3 with Ce(IV) in CHCl3 generates relatively stable Pd(II)-phenoxyl radical complex (g = 2.0073). The results related with the chemical oxidation of 2 and 3 as well as the catalytic activity of 3 in the hydrogenation of PhNO2 are presented.