1229311-65-2

Basic information

• Product Name: (-)-menthyl 2-acetamido-3,4,6-tri-O-benzyl-2-deoxy-β-D-glucopyranoside
• Synonyms: (-)-menthyl 2-acetamido-3,4,6-tri-O-benzyl-2-deoxy-β-D-glucopyranoside
• CAS NO: 1229311-65-2
• Molecular Weight: 629.837
• Mol File: 1229311-65-2.mol

Chemical Properties

• CAS DataBase Reference: (-)-menthyl 2-acetamido-3,4,6-tri-O-benzyl-2-deoxy-β-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: (-)-menthyl 2-acetamido-3,4,6-tri-O-benzyl-2-deoxy-β-D-glucopyranoside(1229311-65-2)
• EPA Substance Registry System: (-)-menthyl 2-acetamido-3,4,6-tri-O-benzyl-2-deoxy-β-D-glucopyranoside(1229311-65-2)

Safety Data

• Hazardous Substances Data: 1229311-65-2(Hazardous Substances Data)

Upstream product

• 2216-51-5 (-)-menthol 
• 147048-57-5 4'-pentenyl 2-acetamido-3,4,6-tri-O-benzyl-2-deoxy-β-D-glucopyranoside 
• 1229311-58-3 phenyl 2-acetamido-3,4,6-tri-O-benzyl-2-deoxy-1-thio-β-D-glucopyranoside 

Relevant articles and documents

Direct chemical glycosylation with pentenyl- and thioglycoside donors of N-acetylglucosamine

The use of pentenyl and thiophenyl glycosides of N-acetylglucosamine (GlcNAc) as glycosyl donors for the direct preparation of O-glycosides of GlcNAc promoted by N-iodosuccinimide (NIS) and metal triflates in dichloromethane has been investigated. Both glycosyl acceptors 1-octanol and (-)-menthol resulted in good glycosylation yields for both types of donors with pentenyl glycosides being somewhat superior in terms of yield. Carbohydrate-based acceptors were reacted with a benzylated GlcNAc-pentenyl donor but only provided disaccharides in poor to moderate yields. The results show that a variety of metal triflates are capable of acting as an activator for both NIS and the intermediate oxazoline.