1229567-08-1Relevant academic research and scientific papers
The first ruthenium-silsesquioxyl complexes-synthesis, structure and mechanistic implications in silylative coupling
Zak, Patrycja,Kubicki, Maciej,Marciniec, Bogdan,Rogalski, Szymon,Pietraszuk, Cezary,Frackowiak, Dawid
, p. 7911 - 7916 (2014/05/20)
The first ruthenium-silsesquioxyl complexes have been synthesised and characterized via spectroscopic and X-ray methods. Mechanistic studies were performed and the complexes obtained were proved to be intermediates in the catalytic cycle of silylative coupling of olefins with vinylsilsesquioxane. Moreover, a mechanism for silylative coupling of styrene with vinylsilsesquioxanes was proposed. This journal is the Partner Organisations 2014.
Efficient functionalisation of cubic monovinylsilsesquioxanes via cross-metathesis and silylative coupling with olefins in the presence of ruthenium complexes
Zak, Patrycja,Pietraszuk, Cezary,Marciniec, Bogdan,Spolnik, Brzegorz,Danikiewicz, Witold
body text, p. 2675 - 2682 (2010/04/05)
Monovinylheptaisobutylsilsesquioxane undergoes efficient cross-metathesis and silylative coupling with styrenes. Allyl derivatives were successfully tested in cross-metathesis in the presence of first generation Grubbs' catalyst, while heteroatom-substitu
