1229597-07-2Relevant academic research and scientific papers
PdII-catalyzed oxidative 1,1-diarylation of terminal olefins
Werner, Erik W.,Urkalan, Kaveri B.,Sigman, Matthew S.
supporting information; experimental part, p. 2848 - 2851 (2010/08/20)
(Figure presented) Evaluation of the scope of a PdII-catalyzed oxidative 1,1-diarylation reaction of terminal olefins using aryl stannanes is reported. The reaction is shown to be tolerant of functionality commonly encountered in organic synthesis; however, the reaction outcome was found to be dependent on the nature of the aryl stannane used. A mechanistic rationale for the observation of this influence is provided.
