122961-06-2Relevant academic research and scientific papers
Aromatic C-Nitroso Compounds. Thermodinamics and Kinetics of the Equilibrium between 2,6-Dimethylnitrosobenzene and its trans-Dimer
Azoulay, Michel,Lippman, Richard,Wettermark, Gunnar
, p. 256 - 259 (2007/10/02)
Using i.r.,n.m.r. and visible spectrophotometry, the system 2,6-dimethylnitrosobenzene (DMNB) = 2,2',6,6'-tetramethylazodioxybenzene (TMAB) was investigated.In the solid state, the stable species is trans-TMAB.In acetonitrile solution, the following thermodynamic and activation parameter were derived for the reaction trans-TMAB = 2 DMAB ΔS0 -129 JK-1mol-1, and ΔS++ -6 JK-1mol-1.There was no evidence for the existence of cis-TMAB in solution.
