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122968-01-8

K(1+)*{ReH4(P(CH3)2C6H5)3}(1-)=K{ReH4(P(CH3)2C6H5)3} is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 122968-01-8 Structure

  • Basic information

    1. Product Name: K(1+)*{ReH4(P(CH3)2C6H5)3}(1-)=K{ReH4(P(CH3)2C6H5)3}
    2. Synonyms:
    3. CAS NO:122968-01-8
    4. Molecular Formula:
    5. Molecular Weight: 643.784
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 122968-01-8.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: K(1+)*{ReH4(P(CH3)2C6H5)3}(1-)=K{ReH4(P(CH3)2C6H5)3}(CAS DataBase Reference)
    10. NIST Chemistry Reference: K(1+)*{ReH4(P(CH3)2C6H5)3}(1-)=K{ReH4(P(CH3)2C6H5)3}(122968-01-8)
    11. EPA Substance Registry System: K(1+)*{ReH4(P(CH3)2C6H5)3}(1-)=K{ReH4(P(CH3)2C6H5)3}(122968-01-8)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 122968-01-8(Hazardous Substances Data)

122968-01-8 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 122968-01-8 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 1,2,2,9,6 and 8 respectively; the second part has 2 digits, 0 and 1 respectively.
Calculate Digit Verification of CAS Registry Number 122968-01:
(8*1)+(7*2)+(6*2)+(5*9)+(4*6)+(3*8)+(2*0)+(1*1)=128
128 % 10 = 8
So 122968-01-8 is a valid CAS Registry Number.

122968-01-8Upstream product

122968-01-8Downstream Products

122968-01-8Relevant articles and documents

Synthesis, Structure, and Applications of Transition-Metal Polyhydride Anions

Alvarez, Daniel,Lunquist, Eric G.,Ziller, Joseph W.,Evans, William J.,Caulton, Kenneth G.

, p. 8392 - 8398 (1989)

KH is used to deprotonate ReH7L2 (L = PMe2Ph, PMePh2, and PPh3) and ReH5P3 and WH6P3 (P = PMe2Ph) in THF, and the resulting anions are characterized by variable-temperature multinuclear NMR.The solid-state structure of K(THF)2ReH6(PPh3)2 was determined by X-ray diffraction and revealed a centrosymmetric dimer connected by bridging hydrogen atoms as follows: (μ-H)>2(μ3-H)4.Crystallographic data (213 K): a = 10.987(2), b = 27.134(4), c = 14.030(2) Angstroem; β = 96.609(13) deg; V = 4154.6(11) Angstroem3, and Z = 2 in space group P21/n.The reaction of KD with ReH7(PPh3)2 gave HD and ReH6(PPh3)2(-), thus supporting the idea that the synthetic reaction is in fact proton transfer and ruling out a mechanism consisting of addition of KD to unsaturated ReH5(PPh3)2.LiRuH3(PPh3)3 reacts with 1/2 2 to give (COD)Rh(μ-H)3Ru(PPh3)3 as the kinetic product; this then rearranges (t1/2 = 40 min) in solution to give the thermodynamic isomer (COD)RhH(μ-H)Ru(H)(PPh3)3.

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