123003-47-4

Basic information

• Product Name: baconipyrone C
• Synonyms: baconipyrone C;6-Ethyl-3,5-dimethyl-2-[(1S,3S,4R,5R)-1,3,5-trimethyl-2,6-dioxo-4-hydroxy-6-[[(4R,6R)-4,6-dimethyl-3,7-dioxononan-5-yl]oxy]hexyl]-4H-pyran-4-one
• CAS NO: 123003-47-4
• Molecular Formula: C29H44 O8
• Molecular Weight: 520.6549
• Mol File: 123003-47-4.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 667.8°Cat760mmHg
• Flash Point: 209.4°C
• Appearance: /
• Density: 1.086g/cm³
• Vapor Pressure: 1.1E-20mmHg at 25°C
• Refractive Index: 1.49
• CAS DataBase Reference: baconipyrone C(CAS DataBase Reference)
• NIST Chemistry Reference: baconipyrone C(123003-47-4)
• EPA Substance Registry System: baconipyrone C(123003-47-4)

Safety Data

• Hazardous Substances Data: 123003-47-4(Hazardous Substances Data)

Usage

InChI:InChI=1/C29H44O8/c1-11-20(30)15(4)26(16(5)21(31)12-2)37-28(35)29(9,10)27(34)17(6)22(32)14-24-19(8)25(33)18(7)23(13-3)36-24/h15-17,26-27,34H,11-14H2,1-10H3/t15-,16-,17?,27?/m1/s1

Upstream product

• 944913-78-4 (2R,3R,4S,6S)-6-(6-Ethyl-3,5-dimethyl-4-oxo-4H-pyran-2-yl)-3-(4-methoxy-benzyloxy)-2,4-dimethyl-5-oxo-heptanoic acid 
• 1026344-34-2 (2R,3S,4S,6S)-6-(6-Ethyl-3,5-dimethyl-4-oxo-4H-pyran-2-yl)-3-(4-methoxy-benzyloxy)-2,4-dimethyl-5-oxo-heptanal 
• 158783-80-3 2-[(1R,2R,3R,4S,5S)-2,6-Dihydroxy-4-(4-methoxy-benzyloxy)-1,3,5-trimethyl-hexyl]-6-ethyl-3,5-dimethyl-pyran-4-one 
• 944913-77-3 C₃₈H₆₆O₆Si₂ 
• 944913-66-0 C₁₁H₂₀O₃ 
• 944913-81-9 C₁₃H₂₄O 
• 944913-64-8 C₁₆H₂₈O 
• 944913-82-0 C₃₇H₅₂O₉ 

Relevant articles and documents

Chiral N-heterocyclic carbenes in natural product synthesis: Application of Ru-catalyzed asymmetric ring-opening/cross-metathesis and Cu-catalyzed allylic alkylation to total synthesis of baconipyrone C

(Chemical Equation Presented) Chiral carbenes as major players: Two recently discovered chiral N-heterocyclic carbene (NHC) complexes play a crucial role in a concise enantioselective total synthesis of baconipyrone C (see scheme). An (NHC)Cu complex catalyzes a double asymmetric allylic alkylation (AAA), and an (NHC)Ru complex catalyzes an asymmetric ring-opening/cross- metathesis (AROM/CM) to establish the absolute configuration of the target. RCM = ring-closing metathesis.