123085-55-2

Upstream product

• 123085-56-3 3-(1,5-dimethylhex-4-en-1-yl)-6-methylbenzene-1,2-diol 
• 74-88-4 methyl iodide 
• 1384950-10-0 2-(6-isopropenyl-2-methoxy-3-methyl-phenoxy)-propionic acid methyl ester 
• 1384950-13-3 2-(6-isopropenyl-2-methoxy-3-methyl-phenoxy)-2-methyl-propionic acid methyl ester 
• 1384950-15-5 2-(6-isopropenyl-2-methoxy-3-methyl-phenoxy)-2-methyl-propionic acid 
• 1384950-17-7 (Z)-9-methoxy-2,2,5,8-tetramethylbenzo[b]oxepin-3(2H)-one 
• 123085-59-6 6-(1,5-dimethyl-hex-4-enyl)-2-methoxy-3-methyl-phenol 
• 1384950-08-6 6-isopropenyl-2-methoxy-3-methyl-phenol 

Downstream Products

• 5574-34-5 mansonone C 

Relevant academic research and scientific papers

Radical induced fragmentation in a benzoxocane ring system: Application to the synthesis of elvirol and a formal synthesis of 7,8-dihydroxycalamenene

A novel radical induced fragmentation in a benzoxocane ring system has been employed for a synthesis of elvirol 8 and an advanced intermediate in the synthesis of 7,8-dihydroxycalamenene 20. The coumarins 9, 22 were taken through a sequence of reactions t

Use of allylic strain to enforce stereochemistry. Direct syntheses of 7,8-dihydroxycalamenene and mansonone C

Direct syntheses of 7,8-dihydroxycalamenene and mansonone C were achieved. The cis-stereochemistry required for the synthesis of 7,8-dihydroxycalamenene was introduced by an intramolecular cyclization directed by allylic strain.