123101-19-9Relevant academic research and scientific papers
Stereoselective Michael additions of titanium "ate" complexes of ketone and ester enolates
Bernardi, Anna,Dotti, Pierfranco,Poli, Giovanni,Scolastico, Carlo
, p. 5597 - 5606 (2007/10/02)
The conjugate addition of Ti "ate" complexes of ketone and ester enolates to α,β-unsaturated carbonyl compounds was studied. The reaction was found to be highly regio- and stereoselective. Compared to the lithium enolates, ketone enolate Ti complexes show
Stereochemistry of the Michael Addition of Ester and Ketone Enolates to α,β-Unsaturated Ketones
Oare, David A.,Heathcock, Clayton H.
, p. 157 - 172 (2007/10/02)
The stereo- and regiochemistry of addition of the enolates of ketones and esters to α,β-unsaturated ketones has been studied.There is a strong correlation between the enolate geometry and adduct stereostructure, with E enolates forming syn products and Z
