123149-75-7

Upstream product

• 100-44-7 benzyl chloride 
• 89300-73-2 allyl 3-O-allyl-αβ-D-glucopyranose 

Downstream Products

• 123149-77-9 (S)-1-((2R,3S,4S,5S,6S)-4,6-Bis-allyloxy-3,5-bis-benzyloxy-tetrahydro-pyran-2-yl)-2-(dimethyl-phenyl-silanyl)-ethanol 
• 123149-77-9 (R)-1-((2R,3S,4S,5S,6S)-4,6-Bis-allyloxy-3,5-bis-benzyloxy-tetrahydro-pyran-2-yl)-2-(dimethyl-phenyl-silanyl)-ethanol 
• 123149-80-4 Acetic acid (2S,3S,4S,5R,6S)-3,5-bis-benzyloxy-2-(3-benzyloxycarbonylamino-propoxy)-6-[(R)-1-benzyloxy-2-(dimethyl-phenyl-silanyl)-ethyl]-tetrahydro-pyran-4-yl ester 
• 123149-81-5 (3-{(2S,3S,4S,5S,6S)-3,5-Bis-benzyloxy-6-[(R)-1-benzyloxy-2-(dimethyl-phenyl-silanyl)-ethyl]-4-hydroxy-tetrahydro-pyran-2-yloxy}-propyl)-carbamic acid benzyl ester 
• 123149-79-1 Acetic acid (2S,3S,4S,5S,6R)-3,5-bis-benzyloxy-2-[(R)-1-benzyloxy-2-(dimethyl-phenyl-silanyl)-ethyl]-6-chloro-tetrahydro-pyran-4-yl ester 
• 123149-78-0 Acetic acid (2S,3R,4S,5S,6S)-3,5-bis-benzyloxy-2-[(R)-1-benzyloxy-2-(dimethyl-phenyl-silanyl)-ethyl]-6-hydroxy-tetrahydro-pyran-4-yl ester 
• 123149-76-8 (2S,3S,4S,5S,6S)-4,6-Bis-allyloxy-3,5-bis-benzyloxy-tetrahydro-pyran-2-carbaldehyde 

Relevant academic research and scientific papers

SYNTHESIS OF A SUBSTITUTED 2,6-DIOXABICYCLOHEPTANE, 1,3-ANHYDRO-2,4,6-TRI-O-BENZYL-β-D-GLUCOPYRANOSE

1,3-Anhydro-2,4,6-tri-O-benzyl-β-D-glucopyranose has been synthesized by ring closure of 2,4,6-tri-O-benzyl-α-D-glucopyranosyl chloride via two reaction sequences.The preferable method has allyl 3-O-allyl D-glucopyranoside as key intermediate.This appears to be the first example of an anhydro sugar derivative with the 2,6-dioxabicycloheptane skeleton.