123166-41-6Relevant academic research and scientific papers
DIASTEREOSELECTIVE CYCLIZATION OF 6-OCTEN-1-ALS WITH RHODIUM(I)-COMPLEX
Funakoshi, Kazuhisa,Togo, Nagako,Sakai, Kiyoshi
, p. 1095 - 1098 (1989)
Rhodium(I)-catalyzed cyclization of 6-octen-1-al with chiral protecting group ((4R,6R)-dimethyl-1,3-dioxane) at the C3 afforded diastereoselectively the trans-cyclohexanol.
Diastereoselective cyclization of 6-octen-1-als with Rhodium(I)-complex
Funakoshi, Kazuhisa,Togo, Nagako,Taura, Yukari,Sakai, Kiyoshi
, p. 1776 - 1779 (2007/10/02)
In Rh(I) (Wilkinson)-catalyzed cyclization of 6-octen-1-als, the formation of cis-cyclohexanols is in contrast to Lewis acid-catalyzed cyclization, which affords predominantly the trans-cyclohexanols.However, 6-octen-1-als with a cyclic acetal (1,3-dioxan
