123172-69-0Relevant academic research and scientific papers
Catalytic enantioselective synthesis of quaternary all-carbon stereogenic centers. Preparation of α,α′-disubstituted β,γ-unsaturated esters through Cu-catalyzed asymmetric allylic alkylations
Murphy, Kerry E.,Hoveyda, Amir H.
, p. 1255 - 1258 (2007/10/03)
(Chemical Equation Presented) Peptide-based chiral ligands, readily prepared from commercially available materials, are used to promote Cu-catalyzed asymmetric allylic alkylations of α,β-unsaturated esters bearing a γ-phosphate with various alkylzinc reagents. These transformations lead to the formation of α,α′-dialkyl-β,γ-unsaturated esters in high yields as well as high regio- (re) and enantloselectivities (ee).
GLYCOLALDEHYDE MONOMER IN ORGANIC SYNTHESIS
Dinprasert, P.,Mahidol, C.,Thebtaranonth, C.,Thebtaranonth, Y.
, p. 1149 - 1152 (2007/10/02)
The lithium alkoxide of glycolaldehyde can be generated and trapped in situ by keto- and ester enolates to yield the corresponding keto-epoxides and hydroxy lactones respectively.
