1231894-78-2

Basic information

• Product Name: (bromodifluoromethyl)diphenylsulfonium trifluoromethanesulfonate
• Synonyms: (bromodifluoromethyl)diphenylsulfonium trifluoromethanesulfonate
• CAS NO: 1231894-78-2
• Molecular Weight: 465.26
• Mol File: 1231894-78-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (bromodifluoromethyl)diphenylsulfonium trifluoromethanesulfonate(CAS DataBase Reference)
• NIST Chemistry Reference: (bromodifluoromethyl)diphenylsulfonium trifluoromethanesulfonate(1231894-78-2)
• EPA Substance Registry System: (bromodifluoromethyl)diphenylsulfonium trifluoromethanesulfonate(1231894-78-2)

Safety Data

• Hazardous Substances Data: 1231894-78-2(Hazardous Substances Data)

Upstream product

• 358-23-6 trifluoromethylsulfonic anhydride 
• 154357-93-4 sodium bromodifluoromethanesulfinate 
• 71-43-2 benzene 

Downstream Products

• 82477-43-8 bromodifluoromethylphenylacetylene 
• 842142-04-5 1-(3-bromo-3,3-difluoro-1-propynyl)-4-methoxybenzene 

Relevant articles and documents

New electrophilic bromodifluoromethylation and pentafluoroethylation reagents

S-(fluoroalkyl)diphenylsulfonium salts have been successfully synthesized from the reaction between fluoroalkylsul-finates and triflic anhydride in dichloromethane through a one-pot procedure. These S-(fluoroalkyl) diphenylsulfonium salts have been demonstrated to be effective reagents to fluoroalkylate C-nucleophilic substrates. Ionic substitution and radical or halogenophilic mechanism might be all involved in the reactions. Georg Thieme Verlag Stuttgart - New York.