123224-08-8Relevant articles and documents
Activation of Dichloromethane by Palladium(0) and Platinum(0) Phosphine Complexes: Synthesis and Structure of M(CH2Cl)>(BPh4), M= Pd, Pt
Ghilardi, Carlo A.,Midollini, Stefano,Moneti, Simonetta,Orlandini, Annabella,Ramirez, Jose A.
, p. 304 - 306 (1989)
The Pd(0) trico-ordinate out-of-plane (np3)Pd , and the Pt(0) pseudotetrahedral (np3)Pt(PPh3) complexes react, under mild conditions, with CH2Cl2 yielding (M-CH2-Cl) complexes; BPh4*CH2Cl2 has been structurally charac