123224-08-8

Upstream product

• 12120-15-9 ethylenebis(triphenylphosphine)platinum⁽⁰⁾ 
• 15114-55-3 tris(2-(diphenylphosphino)ethyl)amine 

Downstream Products

• 126688-75-3 {(N(C₂H₄P(C₆H₅)2)3)PtHgCH₃}⁽¹⁺⁾*B(C₆H₅)4^(1-)={(N(C₂H₄P(C₆H₅)2)3)PtHgCH₃}B(C₆H₅)4 
• 452281-86-6 (iodo){tris(2-diphenylphosphino-κP-ethyl)amine-κN}platinum iodide 
• 132108-30-6 {(N(CH₂CH₂P(C₆H₅)2)3)PtAs(C₆H₅)2}⁽¹⁺⁾*B(C₆H₅)4^(1-)={(N(CH₂CH₂P(C₆H₅)2)3)PtAs(C₆H₅)2}B(C₆H₅)4 
• 132108-28-2 {(N(CH₂CH₂P(C₆H₅)2)3)PtAs(CH₃)2}⁽¹⁺⁾*B(C₆H₅)4^(1-)={(N(CH₂CH₂P(C₆H₅)2)3)PtAs(CH₃)2}B(C₆H₅)4 
• 123224-15-7 (hydrido){tris(2-diphenylphosphino-κP-ethyl)amine-κN}platinum tetraphenylborate 
• 126859-80-1 {(N(C₂H₄P(C₆H₅)2)3)PtSn(CH₃)3}⁽¹⁺⁾*B(C₆H₅)4^(1-)={(N(C₂H₄P(C₆H₅)2)3)PtSn(CH₃)3}B(C₆H₅)4 

Relevant academic research and scientific papers

Activation of Dichloromethane by Palladium(0) and Platinum(0) Phosphine Complexes: Synthesis and Structure of M(CH2Cl)>(BPh4), M= Pd, Pt

The Pd(0) trico-ordinate out-of-plane (np3)Pd , and the Pt(0) pseudotetrahedral (np3)Pt(PPh3) complexes react, under mild conditions, with CH2Cl2 yielding (M-CH2-Cl) complexes; BPh4*CH2Cl2 has been structurally charac

Platinum Complexes of the Tripod-like Ligand Tris(2-diphenylphosphinoethyl)amine (tdpea). X-Ray Crystal Structure of BPh4

Treatment of with the tripod-like ligand tris(2-diphenylphosphinoethyl)amine, N(CH2CH2PPh2)3 (tdpea), affords the tetrahedral derivative .This species undergoes oxdative-addition reactions allowing the preparation of alkyl, hydrido, chloromethyl, and iodo five-co-ordinated species.An X-ray structure determnation for the chloromethyl derivative has been carried out.Crystal data: monoclinic, space group P21/n, a=34.601(9), b=17.136(5), c=10.718(3) Angstroem, β=94.56(8) deg, and Z=4.The structure has been solved by three-dimensional Patterson and Fourier syntheses and refined by least squares to a conventional R value of 0.069.