1232394-61-4

Basic information

• Product Name: [(PhC(N(t-Bu))2)GeN(Ph)]2
• CAS NO: 1232394-61-4
• Molecular Weight: 790.127
• Mol File: 1232394-61-4.mol

Chemical Properties

• CAS DataBase Reference: [(PhC(N(t-Bu))2)GeN(Ph)]2(CAS DataBase Reference)
• NIST Chemistry Reference: [(PhC(N(t-Bu))2)GeN(Ph)]2(1232394-61-4)
• EPA Substance Registry System: [(PhC(N(t-Bu))2)GeN(Ph)]2(1232394-61-4)

Safety Data

• Hazardous Substances Data: 1232394-61-4(Hazardous Substances Data)

Upstream product

• 1076188-94-7 [PhC(NtBu)₂Ge]₂ 
• 1227476-15-4 Azobenzene 

Relevant articles and documents

Reactivity studies of a GeI?GeI compound with and without cleavage of the ge?ge bond

This Communication describes two strikingly different reactivities of a digermylene [{PhC(NtBu)2}2Ge2] (1) featuring a GeI?GeI single bond. In the reaction with azobenzene, 1 affords the oxidative addition product LGeN(Ph)N(Ph)GeL [2; L = PhC(NtBu) 2], with simultaneous cleavage of the Ge?Ge bond, whereas treatment of 1 with Fe2(CO)9 yields the Lewis acid?base adduct LGe[Fe(CO)4]Ge[(Fe(CO)4]L (3). Both compounds were characterized by single-crystal X-ray diffraction, NMR spectroscopy, electrospray ionization mass spectrometry, and elemental analysis.