1232672-41-1Relevant articles and documents
Chemoselective reductive cross-coupling of 1,5-diene-3-ols with alkynes: A facile entry to stereodefined skipped trienes
Diez, Peter S.,Micalizio, Glenn C.
scheme or table, p. 9576 - 9578 (2010/08/20)
A convergent synthesis of highly substituted and stereodefined skipped polyenes is described from the reductive cross-coupling of substituted 1,5-diene-3-ols with alkynes. The control of site selectivity in functionalization of the substituted diene is a central feature of this complex fragment union reaction.