123270-13-3Relevant academic research and scientific papers
Regioselective functionalization of unprotected myo-inositol by electrophilic substitution
Watanabe, Yutaka,Uemura, Tsuyoshi,Yamauchi, Satoe,Tomita, Kousei,Saeki, Takafumi,Ishida, Ryousuke,Hayashi, Minoru
, p. 4657 - 4664 (2013/06/26)
Unprotected myo-inositol was treated with various electrophiles, such as aroyl chlorides, tosyl chloride and tert-butyldiphenylsilyl chloride in a solution of LiCl/DMA or DMSO to afford regioselectively 1,3-di-O-substituted or racemic 1-O-substituted deri
One-step regioselective functionalization of myo-inositol by dissolution strategy
Yamauchi, Satoe,Hayashi, Minoru,Watanabe, Yutaka
experimental part, p. 2287 - 2290 (2009/12/06)
Functionalizations of hydroxy groups of myo-inositol were usually nonselective due to its poor solubility. By dissolving myo-inositol in DMSO or LiCl-N,N-dimethylacetamide, we have achieved regioselective acylation, silylation, sulfonylation, phosphinylat
Highly Efficient Protection by the Tetraisopropyldisiloxane-1,3-diyl Group in the Synthesis of myo-Inositol Phosphates as Inositol 1,3,4,6-tetrakisphosphate
Watanabe, Yutaka,Mitani, Motohiro,Morita, Takao,Ozaki, Shoichiro
, p. 482 - 483 (2007/10/02)
Regioselective introduction of the tetraisopropyldisiloxane-1,3-diyl group onto myo-inositol and 1,2-O-cyclohexylidene-myo-inositol realised the efficient synthesis of various myo-inositol phosphates.
