123287-46-7

Upstream product

• 89117-85-1 (5S,12'E,14'E)-1-benzoyl-5-benzyl-3-(1'-oxohexadeca-12',14'-dienyl)-3-phenylselenopyrrolidin-2-one 
• 89117-81-7 (12E,14E)-1-(imidazol-1-yl)hexadeca-12,14-dien-1-one 
• 89117-84-0 (12'E,14'E)-5-benzyl-1-(dimethyl-t-butylsilyl)-3-(1-oxodeca-12,14-dienyl)-3-phenylselenopyrrolidin-2-one 
• 89117-83-9 (5R,12'E,14'E)-5-benzyl-1-(dimethyl-t-butylsilyl)-3-(1'-oxohexadeca-12',14'-dienyl)pyrrolidin-2-one 

Downstream Products

• 89117-79-3 (5S,8R)-2-benzoyl-10-phenyl-12-normethyl<13>cytochalas-6(7)-ene-1,23-dione 
• 89117-79-3 2-benzoyl-10-phenyl-12-normethyl<13>cytochalas-6(7)-ene-1,23-dione 

Relevant academic research and scientific papers

Cytochalasan Synthesis: Macrocycle Synthesis Using Intramolecular Diels-Alder Reactions. X-Ray Crystal Structure of 10-Phenylcytochalasa-6(7),13t-diene-1,21-dione

An approach to the total synthesis of cytochalasans has been developed which makes use of an intramolecular Diels-Alder reaction to close the large ring simultaneously forming the hydrogenated isoindolone unit with the desired stereochemistry.Conjugated t