123287-99-0

Basic information

• Product Name: (1R,2S,6S)-4,4-Dimethyl-7-oxa-bicyclo[4.1.0]heptan-2-ol
• CAS NO: 123287-99-0
• Molecular Weight: 142.198
• Mol File: 123287-99-0.mol

Chemical Properties

• CAS DataBase Reference: (1R,2S,6S)-4,4-Dimethyl-7-oxa-bicyclo[4.1.0]heptan-2-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (1R,2S,6S)-4,4-Dimethyl-7-oxa-bicyclo[4.1.0]heptan-2-ol(123287-99-0)
• EPA Substance Registry System: (1R,2S,6S)-4,4-Dimethyl-7-oxa-bicyclo[4.1.0]heptan-2-ol(123287-99-0)

Safety Data

• Hazardous Substances Data: 123287-99-0(Hazardous Substances Data)

Upstream product

• 17421-93-1 (1SR,6SR)-4,4-dimethyl-7-oxabicyclo[4.1.0]heptan-2-one 
• 123257-47-6 2-Benzenesulfinyl-5,5-dimethyl-cyclohexanone 
• 123257-46-5 5,5-dimethyl-2-phenylsulfanylcyclohexanone 
• 2979-19-3 3,3-dimethylcyclohexanone 
• 4694-17-1 5,5-dimethlycyclohex-2-en-1-one 
• 6267-39-6 3-ethoxy-5,5-dimethyl-2-cyclohexen-1-one 
• 17421-93-1 4,4-dimethyl-7-oxabicyclo[4.1.0]heptan-2-one 

Relevant articles and documents

TOTAL SYNTHESIS OF THE ELEMANOLIDES (+/-) ZEMPOALIN A AND B

Starting with a suitable trisubstituted cyclohexanone derivative two further substituents were introduced via an epoxy ketone which after reduction was reacted with the diethylaluminium derivative of ethoxyacetylene.The resulting dihydroxyester afforded t

Mechanism of Cyclopentene-1-carboxaldehyde Formation by Ring Contraction of 2,3-Epoxycyclohexanols. Improved Synthetic Procedures

Complete analysis of the reaction mixtures from lithium bromide induced skeletal rearrangement of cis- and trans-1-deuterio-4,4-dimethyl-2,3-epoxycyclohexanol (4d and 7d) showed that the formation of specifically deuterated 5,5- and 3,3-dimethylcyclopente